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P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines

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Access status: Embargo until 2050-01-01 , 2009TetrahedronLettLiSupp.pdf (81.54 KB)
Access status: Embargo until 2050-01-01 , 2009TetrahedronLettLi.pdf (1.49 MB)
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Publication date

2009

Authors

Li, J.
Minnaard, A.J.
Klein Gebbink, R.J.M.ISNI 0000000388707889
van Koten, G.ISNI 0000000389131797

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Abstract

The P0CP0-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obtained in moderate to high yields in DMF under very mild conditions and a high yielding and convenient deprotection of the N,N-dimethylsulfamoyl group is also demonstrated.

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International (English)

Citation

Li, J, Minnaard, A J, Klein Gebbink, R J M & van Koten, G 2009, 'P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines', Tetrahedron Letters, vol. 50, pp. 2232-2235. < http://www.elsevier.com >

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https://dspace.library.uu.nl/handle/1874/40061