Catena-Poly[[bis(acetonitrile-κN)manganese(II)]-bis(μ-trifluoromethanesulfonato-κ2O:O')]
Files
Publication date
2009
Authors
Lutz, M.
Schreurs, A.M.M.
Spek, A.L.
Moelands, M.A.H.
Klein Gebbink, R.J.M.
Editors
Advisors
Supervisors
DOI
Document Type
Article
Metadata
Show full item recordCollections
License
Abstract
The title compound, [Mn(CF3SO3)2(CH3CN)2]n, has an MnII cation on an inversion centre in an octahedral environment. The trifluoromethanesulfonate anions act as bridging ligands and form a one-dimensional coordination polymer in the direction of the a axis. The F atoms of the trifluoromethanesulfonate anions form layers parallel to the ab plane, but despite short intermolecular distances, no stabilizing F...F interactions are detected. The Mn—N and C—C bonds of the acetonitrile ligand are analyzed according to the Hirshfeld rigid-bond test. Renninger effects in the reflection data are considered, explored and discussed.
Keywords
Citation
Lutz, M, Schreurs, A M M, Spek, A L, Moelands, M A H & Klein Gebbink, R J M 2009, 'Catena-Poly[[bis(acetonitrile-κN)manganese(II)]-bis(μ-trifluoromethanesulfonato-κ2O:O')]', Acta Crystallographica. Section C, Crystal Structure Communications, vol. 66, no. 1, pp. m9-m12.