The potential and concentration dependency of the adsorption of lead(II) at the mercury-1 M KCl solution interface
Publication date
1972-07
Authors
Sluyters-Rehbach, M.
Breukel, J.S.M.C.
Wijnhorst, C.A.
Sluyters, J.H.
Gijsbertsen, K.A.
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Article
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Abstract
It is shown that when lead ions are adsorbed at the mercury-1 M KCl solution interface the interface structure changes abruptly at certain potentials at higher Pb(II) concentrations. This is demonstrated by means of double-layer capacity measurements, chronocoulometric experiments and preliminarily by the inhibition phenomena in the d.c. polarogram of Bi(III).