A π-extended β-diketiminate ligand via a templated Scholl approach

Publication date

2024

Authors

Killian, LarsISNI 0000000512545195
Lutz, M.ORCID 0000-0003-1524-9629ISNI 0000000352600916
Thevenon, ArnaudISNI 0000000472293471

Editors

Advisors

Supervisors

Document Type

Article
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License

cc_by

Abstract

We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.

Keywords

Electronic, Optical and Magnetic Materials, Catalysis, Ceramics and Composites, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Materials Chemistry

Citation

Killian, L, Lutz, M & Thevenon, A 2024, 'A π-extended β-diketiminate ligand via a templated Scholl approach', Chemical Communications, vol. 60, no. 52, pp. 6663–6666. https://doi.org/10.1039/d4cc01627k