Mechanism of olefin epoxidation by a mono-oxygenase model
Publication date
1984
Authors
Nolte, R.J.M.
Razenberg, J.A.S.J.
Drenth, W.
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Article
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Abstract
Kinetic data suggest that the rate determining step in the epoxidation of cyclohexene by Mn-TPP and sodium hypochlorite is the conversion of a Mn(III)-species into an oxo-manganese(V)-species.