A π-extended β-diketiminate ligand via a templated Scholl approach
Publication date
2024
Authors
Killian, Lars
Lutz, Martin
Thevenon, Arnaud
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Document Type
Article
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Abstract
We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.
Keywords
Electronic, Optical and Magnetic Materials, Catalysis, Ceramics and Composites, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Materials Chemistry
Citation
Killian, L, Lutz, M & Thevenon, A 2024, 'A π-extended β-diketiminate ligand via a templated Scholl approach', Chemical Communications, vol. 60, no. 52, pp. 6663–6666. https://doi.org/10.1039/d4cc01627k