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A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

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Publication date

2017-01-18

Authors

Botez, Laurian
de Jong, G. Bas
Slootweg, J. Chris
Deelman, Berth JanISNI 0000000389428531

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DOI

https://doi.org/10.1002/ejoc.201601222

Document Type

Article

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Abstract

In this contribution we present the direct conversion of sodium phosphinate (NaH2PO2·H2O) to symmetrical sodium diarylphosphinates and their corresponding acids by using palladium catalysis. This route eliminates the need for chlorinated precursors, such as PCl3 and intermediate alkyl- or ammoniumphosphinates.

Keywords

Cross-coupling, Homogeneous catalysis, Industrial chemistry, Palladium, Phosphinates, Sustainable chemistry, Physical and Theoretical Chemistry, Organic Chemistry

Citation

Botez, L, de Jong, G B, Slootweg, J C & Deelman, B J 2017, 'A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate', European Journal of Organic Chemistry, vol. 2017, no. 3, pp. 434-437. https://doi.org/10.1002/ejoc.201601222

URI

https://dspace.library.uu.nl/handle/1874/350845