Transferability of dipole moment derivatives: A general method for the calculation of absolute rotational contributions
Publication date
1979-06-01
Authors
Smit, W.M.A.
Bode, J.H.G.
Straten, A.J. van
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Article
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Abstract
A general method for the calculation of absolute rotational corrections for the dipole moment derivatives is given based on the definition of pure geometrical distortions. The method is generally valid and allows the rotational contributions to be calculated for all modes of any molecule. The relation between absolute and relative corrections is discussed and the method is demonstrated by calculating the rotational corrections for a few asymmetrical molecules.