A phosphorus analogue of Bis(η4-cyclobutadiene)iron(0)
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Publication date
2009
Authors
Wolf, Robert
Slootweg, J.C.
Ehlers, A.W.
Hartl, F.
de Bruin, B.
Lutz, M.
Spek, A.L.
Lammertsma, K.
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Abstract
P makes it possible: the convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(4-P2C2tBu2)2] (see structure) suggests that the elusive all-carbon complex [Fe(4-C4H4)2] is a viable synthetic target.
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Wolf, R, Slootweg, J C, Ehlers, A W, Hartl, F, de Bruin, B, Lutz, M, Spek, A L & Lammertsma, K 2009, 'A phosphorus analogue of Bis(η4-cyclobutadiene)iron(0)', Angewandte Chemie-International Edition, vol. 48, no. 17, pp. 3104-3107.