Log In

Crystallographic Space Group Choice and Its Chemical Consequences: Revised Crystal Structure of [Fe(phen)2Cl2]NO3

Files

Access status: Embargo until 2050-01-01 , 2467_ftp.pdf (362.32 KB)
How and where to find an Open Access version of this publication?

Publication date

2013

Authors

Huang, YISNI 0000000492975058
Moret, Marc-EtienneORCID 0000-0002-3137-6073ISNI 0000000436414547
Klein Gebbink, Robertus J.M.ISNI 0000000388707889
Lutz, MartinORCID 0000-0003-1524-9629ISNI 0000000352600916

Editors

Advisors

Supervisors

DOI

https://doi.org/10.1002/ejic.201201452

Document Type

Article

Metadata

Show full item record

Collections

Utrecht University Repository
Open Access logo

License

Abstract

The crystal structure of [Fe(phen)2Cl2]NO3, recently published in the C2/c space group, has been redetermined. The revised structure is shown to belong to the lower symmetry space group Cc and to contain additional water and acetic acid solvent molecules involved in one-dimensional, hydrogen-bonded chains incorporating the nitrate counterion. Accordingly, crystals obtained by means of the reported procedure should be formulated as [Fe(phen)2Cl2]NO3·CH3COOH·H2O for proper use in further experiments.

Keywords

Citation

Huang, Y, Moret, M, Klein Gebbink, R J M & Lutz, M 2013, 'Crystallographic Space Group Choice and Its Chemical Consequences: Revised Crystal Structure of [Fe(phen)2Cl2]NO3', European Journal of Inorganic Chemistry, vol. 2013, no. 13, pp. 2467-2469. https://doi.org/10.1002/ejic.201201452

URI

http://hdl.handle.net/1874/290554