Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement
Publication date
2011
Authors
Lyaskovskyy, V.
Elders, N.
Ehlers, A.W.
Lutz, Martin
Slootweg, J.C.
Lammertsma, K.
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Abstract
In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.
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Lyaskovskyy, V, Elders, N, Ehlers, A W, Lutz, M, Slootweg, J C & Lammertsma, K 2011, 'Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement', Journal of the American Chemical Society, vol. 133, no. 25, pp. 9704-9707. https://doi.org/10.1021/ja203083c