Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions

Publication date

1990-01-13

Authors

Doyle, M.P.
Brandes, B.D.
Kazala, A.P.
Pieters, Roland J.ORCID 0000-0003-4723-3584ISNI 0000000391858821
Jarstfer, M.B.
Watkins, L.M.
Eagle, C.T.

Editors

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Supervisors

Document Type

Article

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Abstract

Chiral Rh2L4 (L = 4-substituted-oxalidinones and methyl 2-pyrrolidone-5-carboxylate) having two nitrogen-rhodium bonds in the cis geometry at each rhodium face are effective catalysts for enantioselective intermolecular cyclopropanation reactions.

Keywords

cyclopropane derivative, rhodium, article, catalysis, methodology, nonhuman, priority journal, synthesis

Citation

Doyle, M P, Brandes, B D, Kazala, A P, Pieters, R J, Jarstfer, M B, Watkins, L M & Eagle, C T 1990, 'Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions', Tetrahedron Letters, vol. 31, no. 46, pp. 6613-6616. https://doi.org/10.1016/S0040-4039(00)97128-4