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Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques

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Publication date

2003

Authors

Tromp, M.
Sietsma, J.R.A.
van Bokhoven, J.A.
van Strijdonck, G.P.F.
Haaren, R.J.
van der Eerden, AdISNI 0000000397157444
van Leeuwen, P.W.N.M.
Koningsberger, Diederik C.ISNI 0000000116485020

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DOI

https://doi.org/10.1039/B206758G

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Article

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Abstract

UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.

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Tromp, M, Sietsma, J R A, van Bokhoven, J A, van Strijdonck, G P F, Haaren, R J, van der Eerden, A M J, van Leeuwen, P W N M & Koningsberger, D C 2003, 'Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques', Chemical Communications, vol. 2003, no. 1, pp. 128-129. https://doi.org/10.1039/B206758G

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https://dspace.library.uu.nl/handle/1874/5864