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Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions

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Verhoeven_et_al_2019_European_Journal_of_Inorganic_Chem... (1.04 MB)

Publication date

2019-02-07

Authors

Verhoeven, Dide G. A.ISNI 0000000419570927
Kwakernaak, Joost
Van Wiggen, Maxime A. C.
Lutz, MartinORCID 0000-0003-1524-9629ISNI 0000000352600916
Moret, Marc-EtienneORCID 0000-0002-3137-6073ISNI 0000000436414547

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DOI

https://doi.org/10.1002/ejic.201801221

Document Type

Article

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Abstract

The catalytic activity of cobalt(II) and cobalt(I) complexes of the diphosphine ketone ligand pToldpbp is demonstrated in the hydrosilylation of 1‐octene with phenylsilane under mild conditions, showing the first catalytic application of dpbp ligands in combination with base metals.

Keywords

Silane chemistry, Cobalt, Hydrosilylation, Homogeneous catalysis, Cooperative catalysis

Citation

Verhoeven, D G A, Kwakernaak, J, Van Wiggen, M A C, Lutz, M & Moret, M-E 2019, 'Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions', European Journal of Inorganic Chemistry, vol. 2019, no. 5, pp. 660-667. https://doi.org/10.1002/ejic.201801221

URI

http://hdl.handle.net/1874/378155