Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans
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Publication date
2008-05-05
Authors
Van Leeuwen, S. M.
Leeflang, B.R.
Gerwig, G.J.
Kamerling, J.P.
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Article
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Abstract
An NMR study of proton chemical shift patterns of known linear α-d-glucopyranose di- and trisaccharide structures was carried out. Chemical shift patterns for (α1→2)-, (α1→3)-, (α1→4)- and (α1→6)-linked d-glucose residues were analysed and compared to literature data. Using these data, a 1H NMR structural-reporter-group concept was formulated to function as a tool in the structural analysis of α-d-glucans.
Keywords
Structural-reporter-group concept, a-d-Glucan1, H NMR spectroscopy, Polysaccharide structural analysis
Citation
van Leeuwen, S S, Leeflang, B R, Gerwig, G J & Kamerling, J P 2008, 'Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans', Carbohydrate Research, vol. 343, no. 6, pp. 1114-1119. https://doi.org/10.1016/j.carres.2008.01.043