Atropisomeric phosphinines: design and synthesis
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Publication date
2007
Authors
Müller, C.
Pidko, E.A.
Totev, D.
Lutz, Martin
Spek, A.L.
van Santen, R.A.
Vogt, D.
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Abstract
The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.
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Müller, C, Pidko, E A, Totev, D, Lutz, M, Spek, A L, van Santen, R A & Vogt, D 2007, 'Atropisomeric phosphinines: design and synthesis', Dalton Transactions, vol. 2007, no. 46, pp. 5372-5375.