Five-coordinate [PtIICl2(h2-olefin)L2] (L2 = s,s-N,N' bonded a-diimine or N,N'-disubstituted-1,2-diaminoethane) complexes. Solution conformation, h2-olefin rotational barriers (NMR) and X-ray molecular structure of [PtCl2(h2-styrene) (t-Bu-N=CHCH=N=t-Bu)]