Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?
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Publication date
2002-02-04
Authors
Kronenburg, Claudia M.P
Amijs, Catelijne H.M
Wijkens, Peter
Jastrzebski, J.T.B.H.
van Koten, G.
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Article
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Abstract
Oxidative decomposition of cyanocuprates of the type CuLi(CN)Ar (Ar = [C6H4(CH2NMe2)-2]-, 1a) or type CuLi2(CN)Ar2(1b) shows the unexpected formation of aryl-cyanides in up to 30% yield. © 2002 Elsevier Science Ltd. All rights reserved.
Keywords
copper derivative, cyanide, article, decomposition, gas chromatography, ion transport, mass spectrometry, oxidation
Citation
Kronenburg, C M P, Amijs, C H M, Wijkens, P, Jastrzebski, J T B H & Van Koten, G 2002, 'Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?', Tetrahedron Letters, vol. 43, no. 6, pp. 1113-1115. https://doi.org/10.1016/S0040-4039(01)02337-1