Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex - multiple reaction steps at a reactive ligand
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Publication date
2015-08-24
Authors
Oldenhof, S.
Lutz, M.
Van Der Vlugt, J. I.
Reek, J. N H
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Article
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taverne
Abstract
Substrate activation by means of a reactive ligand is a topic of much interest. Herein we describe a stoichiometric anti-Markovnikov C-N bond formation involving ligand reactivity in multiple steps along the reaction coordinate, including ligand assisted substrate (de)protonation and C-N bond formation, as illustrated by a combined experimental, spectroscopic and computational study. This affords a highly unusual four-membered iridacycle bearing an exo-cyclic C=C double bond.
Keywords
Taverne, General Chemistry, Catalysis, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Surfaces, Coatings and Films, Materials Chemistry, Metals and Alloys
Citation
Oldenhof, S, Lutz, M, Van Der Vlugt, J I & Reek, J N H 2015, 'Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex - multiple reaction steps at a reactive ligand', Chemical Communications, vol. 51, no. 82, pp. 15200-15203. https://doi.org/10.1039/c5cc05916j