C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]
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2013
Authors
Broeckx, L.E.E.
Delaunay, W.
Latouche, C.
Lutz, Martin
Boucekkine, A.
Hissler, M.
Müller, Christian
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Abstract
Access to homoleptic phosphinine-based coordination compounds of d6 metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine− iridium(III) complex, obtained by C−H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.
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Broeckx, L E E, Delaunay, W, Latouche, C, Lutz, M, Boucekkine, A, Hissler, M & Müller, C 2013, 'C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]', Inorganic Chemistry, vol. 52, no. 19, pp. 10738-10740. https://doi.org/10.1021/ic401933m