Transcyclometalation, a versatile methodology for multiple metal-carbon bond formation with multisite ligands

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2002

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Dijkstra, H.P.ISNI 0000000390200630
Albrecht, M.
van Koten, G.ISNI 0000000389131797

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Abstract

Transcyclometalation has been successfully applied for the multi-platination and -ruthenation of ‘cartwheel’-type ligand systems containing six potential metal binding sites, thus providing a method for multiple metal–carbon bond formation via C–H bond activation which is superior to established cyclometalation protocols.

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Dijkstra, H P, Albrecht, M & van Koten, G 2002, 'Transcyclometalation, a versatile methodology for multiple metal-carbon bond formation with multisite ligands', Chemical Communications, vol. 2002, no. 2, pp. 126-127.