Inhomogeneous phase transition upon hydrogenation of nanocluster Pd films
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Publication date
2009
Authors
Di Vece, M.
Kelly, J.J.
Lievens, P.
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Article
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Abstract
A combination of electrochemical and optical techniques is used to study the interaction of hydrogen with palladium nanoclusters. Hydrogen pressure-composition isotherms reveal the reduced presence of the phase in palladium nanoclusters. Hydrogen extraction transients relate the reduced miscibility gap to a core-shell phase transformation in the palladium nanoclusters.
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Di Vece, M, Kelly, J J & Lievens, P 2009, 'Inhomogeneous phase transition upon hydrogenation of nanocluster Pd films', ChemPhysChem, vol. 10, no. 3, pp. 512-515.