Log In

Live encapsulation of a Keggin polyanion in NH2-MIL-101(Al) observed by in situ time resolved X-ray scattering

Files

How and where to find an Open Access version of this publication?

Publication date

2011

Authors

Juan-Alcañiz, J.
Goesten, M.
Martinez-Joaristi, A.
Stavitski, I.ISNI 0000000388999295
Petukhov, Andrei VORCID 0000-0001-9840-6014ISNI 0000000389991404
Gascon, J.
Kapteijn, F.

Editors

Advisors

Supervisors

DOI

https://doi.org/10.1039/c1cc12213d

Document Type

Article

Metadata

Show full item record

Collections

Utrecht University Repository

License

Abstract

The templating effect of the Keggin polyanion derived from phosphotungstic acid (PTA) during the synthesis of NH2-MIL- 101(Al) has been investigated by means of in situ SAXS/WAXS. Kinetic analysis and structural observations demonstrate that PTA acts as a nucleation site and that it stabilizes the precursor phase NH2-MOF-235(Al). Surprisingly kinetics of formation are little changed.

Keywords

Citation

Juan-Alcañiz, J, Goesten, M, Martinez-Joaristi, A, Stavitski, I, Petukhov, A V, Gascon, J & Kapteijn, F 2011, 'Live encapsulation of a Keggin polyanion in NH2-MIL-101(Al) observed by in situ time resolved X-ray scattering', Chemical Communications, vol. 47, no. 30, pp. 8578-8580. https://doi.org/10.1039/c1cc12213d

URI

http://hdl.handle.net/1874/235178