Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands
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Publication date
2009
Authors
Bonnet, S.A.
Li, J.
Siegler, Maxime A.
von Chrzanowski, L.S.
Spek, A.L.
van Koten, G.
Klein Gebbink, R.J.M.
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Abstract
Feel the pinch! Planar-chiral, cationic, ruthenium-palladium complexes based on 6,1-coordinated ECE pincer ligands are synthesized as racemic mixtures by reacting ECE-palladium complexes and [Ru(C5R5)(MeCN)3]+ arenophiles (R=H or Me). Chiral resolution of the cationic complexes was achieved by using the chiral counterion [-TRISPHAT]-, and solving the X-ray crystal structure of one diastereoisomer
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International (English)
Citation
Bonnet, S A, Li, J, Siegler, M A M, von Chrzanowski, L S, Spek, A L, van Koten, G & Klein Gebbink, R J M 2009, 'Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands', Chemistry-A European Journal, vol. 15, no. 14, pp. 3340-3343. < http://www.wiley-vch.de >