Bis(acetato-κO)bis(thiourea-κS)cobalt(II)

Publication date

2014-03-01

Authors

Lutz, M.ORCID 0000-0003-1524-9629ISNI 0000000352600916

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Article
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Abstract

The title compound, [Co(CH3COO)2 (CH 4N2S)2], is isotypic with the corresponding ZnII complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N - H⋯O and N - H⋯S hydrogen bonds, leading to a three-dimensional network.

Keywords

Data-to-parameter ratio = 16.2, Mean σ(C-C) = 0.002 Å, R factor = 0.016, Single-crystal X-ray study, T = 150 K, wR factor = 0.041, Condensed Matter Physics, General Materials Science, General Chemistry

Citation

Lutz, M 2014, 'Bis(acetato-κO)bis(thiourea-κS)cobalt(II)', Acta crystallographica. Section E, Structure reports, vol. 70, no. 3, m78. https://doi.org/10.1107/S1600536814002074