Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand

Publication date

2002

Authors

Farrington, E.J.
Martinez Viviente, E.
Williams, S.R.
van Koten, G.ISNI 0000000389131797
Brown, J.M.

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Article

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Abstract

The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the ferrocene.

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Citation

Farrington, E J, Martinez Viviente, E, Williams, S R, van Koten, G & Brown, J M 2002, 'Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand', Chemical Communications, vol. 2002, no. 4, pp. 308-309. https://doi.org/10.1039/B108585A