Dynamic X-ray diffraction computed tomography reveals real-time insight into catalyst active phase evolution

Abstract

Metals and metal oxides anchored to porous support materials are widely used as heterogeneous catalysts in a number of important industrial chemical processes. These catalysts owe their activity to the formation of unique metal/metal oxide support interactions, typically resulting in highly dispersed actives stabilized in a particular electronic or coordination state. They are employed in fixed-bed reactors as extruded or pelletized millimeter-sized “catalyst bodies” minimizing pressure drops along the length of the reactor. Since the efficiency of the whole catalytic system depends on the behavior and efficiency of the catalyst body per se, its design has very great importance. Crucial to this design is an understanding of the factors which influence the distribution and nature of the active phase during preparation. The type of desired distribution is very much dependant on catalytic process and required products; for example, an egg-shell distribution (as opposed to uniform, egg-white, or egg-yolk), where the active phase is located at the edges of the catalyst body, can be favored if the product forms readily.