Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization
Publication date
2009
Authors
Palkovits, Regina
Parvulescu, Andrei N.
Hausoul, P.J.C.
Kruithof, C.A.
Gebbink, Robertus J. M. Klein
Weckhuysen, Bert
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Document Type
Article
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Abstract
The telomerization of 1,3-butadiene with various alcohols has been investigated using a catalyst based on a Pd(acac)(2) precursor and a phosphine ligand, TOMPP (TOMPP = tris-(o-methoxyphenyl)phosphine). We were able to demonstrate the capability of the catalyst to telomerize 1,3-butadiene with various multifunctional nucleophiles having primary and secondary alcohol functions. High yields of telomer products (>98%) were obtained in very short reaction times (
Keywords
Palladium catalysts, Convenient route, Fine chemicals, Butadiene, Efficient, Glycerol, Sucrose, Ligands, Hydrogenation, Dimerization, International (English)
Citation
Palkovits, R, Parvulescu, A N, Hausoul, P J C, Kruithof, C A, Gebbink, R J M K & Weckhuysen, B M 2009, 'Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts : new opportunities for catalytic biomass valorization', Green Chemistry, vol. 11, no. 8, pp. 1155-1160. https://doi.org/10.1039/b904274a