Azine-Linked Covalent Organic Framework (COF)-Based Mixed-Matrix Membranes for CO2/CH4 Separation
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2016-10-04
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Abstract
Mixed‐matrix membranes (MMMs) comprising Matrimid and a microporous azine‐linked covalent organic frameworks (ACOF‐1) were prepared and tested in the separation of CO2 from an equimolar CO2/CH4 mixture. The COF‐based MMMs show a more than doubling of the CO2 permeability upon 16 wt % ACOF‐1 loading together with a slight increase in selectivity compared to the bare polymer. These results show the potential of COFs in the preparation of MMMs.
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Shan, M, Seoane de la Cuesta, B, Rozhko, E, Dikhtiarenko, A, Clet, G, Kapteijn, F & Gascon, J 2016, 'Azine-Linked Covalent Organic Framework (COF)-Based Mixed-Matrix Membranes for CO2/CH4 Separation', Chemistry - A European Journal, vol. 22, no. 41, pp. 14467-14470. https://doi.org/10.1002/chem.201602999