2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)
Publication date
2010
Authors
Campos Carrasco, A.
Pidko, E.A.
Masdeu-Bultó, A. M.
Lutz, M.
Spek, A.L.
Vogt, D.
Müller, C.
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Article
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Abstract
The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.
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Campos Carrasco, A, Pidko, E A, Masdeu-Bultó, A M, Lutz, M, Spek, A L, Vogt, D & Müller, C 2010, '2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)', New Journal of Chemistry, vol. 34, no. 8, pp. 1547-1550. https://doi.org/10.1039/c0nj00030b