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Base-free Pd/TOMPP-Catalyzed Telomerization of 1,3-Butadiene with Carbohydrates and sugar alcohols

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Publication date

2009

Authors

Hausoul, P.J.C.ISNI 0000000396505582
Bruijnincx, P.C.A.ISNI 0000000389623396
Klein Gebbink, R.J.M.ISNI 0000000388707889
Weckhuysen, Bert M.ORCID 0000-0001-5245-1426ISNI 0000000110540180

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DOI

https://doi.org/10.1002/cssc.200900115

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Article

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Abstract

Sugar and alcohol - a superior combo: The telomerization activity of the Pd/TOMPP catalyst is screened using thirteen different biomass-derived carbohydrates and sugar alcohols. High substrate conversions are achieved by using low Pd loading and without the use of an added base. In terms of butadiene conversion, a clear structure-activity relationship is found, which is in line with the series: sugar alcohols>sucrose>aldohexoses>aldopentoses>ketohexoses

Keywords

International (English)

Citation

Hausoul, P J C, Bruijnincx, P C A, Klein Gebbink, R J M & Weckhuysen, B M 2009, 'Base-free Pd/TOMPP-Catalyzed Telomerization of 1,3-Butadiene with Carbohydrates and sugar alcohols', ChemSusChem, vol. 2, no. 9, pp. 855-858. https://doi.org/10.1002/cssc.200900115

URI

https://dspace.library.uu.nl/handle/1874/40928