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Preorganized Frustrated Lewis Pairs

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Publication date

2012

Authors

Bertini, F.
Lyaskovskyy, V.
Timmer, B.J.J.
de Kanter, F.J.J.
Lutz, M.ORCID 0000-0003-1524-9629ISNI 0000000352600916
Ehlers, A.W.
Slootweg, J.C.
Lammertsma, K.

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DOI

https://doi.org/10.1021/ja210214r

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Article

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Abstract

Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH2BPh2 with H2, CO2, and isocyanates and supported computationally.

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Citation

Bertini, F, Lyaskovskyy, V, Timmer, B J J, de Kanter, F J J, Lutz, M, Ehlers, A W, Slootweg, J C & Lammertsma, K 2012, 'Preorganized Frustrated Lewis Pairs', Journal of the American Chemical Society, vol. 134, pp. 201-204. https://doi.org/10.1021/ja210214r

URI

https://dspace.library.uu.nl/handle/1874/269201