Particle shape effects in colloidal crystals and colloidal liquid crystals: Small-angle X-ray scattering studies with microradian resolution
Publication date
2015-08
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Abstract
Small-angle X-ray scattering (SAXS) is an indispensable tool in structural investigations of self-assembled colloidal crystals and colloidal liquid crystals. This paper reviews recent studies of the particle shape effects on the crystal structure as revealed by SAXS. Rod-like, plate-like, biaxial board-like as well as cubic-like shapes are discussed. Since relatively large, (sub)micron particles are often used in these studies, we describe the principles of the microradian X-ray diffraction technique that allows detailed characterisation of the periodic order including the determination of the intrinsic width of the Bragg peaks. (C) 2015 Elsevier Ltd. All rights reserved.
Keywords
Colloidal crystal, Colloidal liquid crystal, Small-angle X-ray, Scattering, Microradian resolution, Anisotropic colloids, AQUEOUS SUSPENSIONS, PHASE-BEHAVIOR, GOETHITE NANORODS, COMPLEX STRUCTURES, MAGNETIC-FIELD, DIFFRACTION, TRANSITIONS, PLATELETS, SUPERLATTICES, DISPERSIONS, Taverne
Citation
Petukhov, A V, Meijer, J-M & Vroege, G J 2015, 'Particle shape effects in colloidal crystals and colloidal liquid crystals : Small-angle X-ray scattering studies with microradian resolution', Current opinion in colloid & interface science, vol. 20, no. 4, pp. 272-281. https://doi.org/10.1016/j.cocis.2015.09.003