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Ionothermal synthesis and crystal structures of metal phosphate chains

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Publication date

2013

Authors

Wragg, D.
Le Ouay, B.
Beale, Andrew M.ISNI 000000039664243X
O'Brien, M.G.ISNI 0000000387386585
Slawin, A.M.Z.
Warren, J.E.
Prior, T.J.
Morris, R.E.

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DOI

https://doi.org/10.1016/j.jssc.2010.05.002

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Article

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Abstract

We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid.

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Citation

Wragg, D, Le Ouay, B, Beale, A M, O'Brien, M G, Slawin, A M Z, Warren, J E, Prior, T J & Morris, R E 2013, 'Ionothermal synthesis and crystal structures of metal phosphate chains', Journal of Solid State Chemistry, vol. 183, no. 7, pp. 1625-1631. https://doi.org/10.1016/j.jssc.2010.05.002

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https://dspace.library.uu.nl/handle/1874/290996