Micro determination of gentamicin in serum by high-performance liquid chromatography with ultraviolet detection

Publication date

1980-05-09

Authors

Barends, D.M.
Sandt, J.S.F. van der
Hulshoff, A.

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Abstract

A procedure for the high-performance liquid chromatographic determination of gentamicin in serum is described using pre-column derivatisation and UV detection. The serum proteins are precipitated with acetonitrile and the gentamicin components in the supernatant are derivatized with 1-fluoro-2,4-dinitrobenzene. The reaction products are chromatographed on a microparticulate C18 reversed-phase column and detected at 365 nm. Sample volumes of 50 μl are sufficient for the determination of gentamicin concentrations in, and well below, the therapeutic range.

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