Synthesis of C60-attached SCS Pincer Palladium(II) Complexes
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Publication date
2003
Authors
Koten, G. van
Meijer, M.D.
Mulder, B.
Klink, G.P.M. van
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Article
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Abstract
The synthesis of C60-attached SCS ligands ([C6H2(CH2SPh)2-2,6-R-4]−) is described. Starting from 4-formyl-SCS-H (2), 1,2-methanofullerene and fulleropyrrolidine SCS ligands were obtained. Subsequent palladation with [Pd(MeCN)4](BF4)2 afforded the corresponding palladium(II) complexes.