Phosphinidene addition to conjugated allenes
Files
Publication date
2009
Authors
Bertini, F.
Wit, J.B.M.
Ünal, M.
de Kanter, F.J.J.
Schakel, M.
Slootweg, J.C.
Ehlers, A.W.
Nijbacker, T.
Komen, C.M.D.
Lutz, M.
Editors
Advisors
Supervisors
DOI
Document Type
Article
Metadata
Show full item recordCollections
License
Abstract
Generating the transient electrophilic tungsten pentacarbonyl-phenylphosphinidene complex PhPW(CO)5 in the presence of 2,7-dimethylocta-2,3,5,6-tetraene leads to the formation of a 3,4-disubstituted phosphole or a complexed phospholene, depending on the reaction conditions. The formation of the phospholene results from the reaction of PhPW(CO)5 with the diallene, while the formation of the phosphole arises from reaction with 3,4-diisopropylidene-cyclobutene, which is formed in situ from the isomerization of the conjugated allene.
Keywords
Citation
Bertini, F, Wit, J B M, Ünal, M, de Kanter, F J J, Schakel, M, Slootweg, J C, Ehlers, A W, Nijbacker, T, Komen, C M D, Lutz, M, Spek, A L & Lammertsma, K 2009, 'Phosphinidene addition to conjugated allenes', Advanced synthesis & catalysis, vol. 351, no. 7-8, pp. 1132-1138.