Non-Gaussian dynamics in smectic liquid crystals of parallel hard rods

Abstract

Using computer simulations, we studied the diffusion and structural relaxation in equilibrium smectic liquidcrystal bulk phases of parallel hard spherocylinders. These systems exhibit a non-Gaussian layer-to-layer diffusion due to the presence of periodic barriers and transient cages and show remarkable similarities with the behavior of out-of-equilibrium supercooled liquids. We detect a very slow interlayer relaxation dynamics over the whole density range of the stable smectic phase which spans a time interval of four time decades. The intrinsic nature of the layered structure yields a hopping-type diffusion which becomes more heterogeneous for higher packing fractions. In contrast, the in-layer dynamics is typical of a dense fluid with a relatively fast decay. Our results on the dynamic behavior agree well with that observed in systems of freely rotating hard rods but differ quantitatively as the height of the periodic barriers reduces to zero at the nematic-smectic transition for aligned rods, while it remains finite for freely rotating rods.