Thermodynamics of irreversible electrochemical phenomena
Publication date
1953
Authors
Groot, S.R. de
Mazur, P.
Tolhoek, H.A.
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DOI
Document Type
Article
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Abstract
A discussion from first principles is given of the energy and entropy laws in electrochemical systems. It is found that it is possible to clarify such controversial concepts as the form of the second law and the role of the electrochemical potential in the systems concerned.