Experimental determination of the mechanical and hydrolytic properties of chitosan/rice husk ash composite membranes

Abstract

Chitosan-based membranes are promising alternatives to synthetic membranes in a number of specialized use cases, including water purification and electrochemical devices. In application, excessive swelling when hydrated can lead to poor mechanical integrity, necessitating modifications to the polymer so as to counter this effect. Embedding inorganic fillers within an organic polymer matrix is one method of combining excellent mechanical stability with good performance. This study investigated the effect of rice husk ash (RHA) on the mechanical and hydrolytic properties of chitosan-based composite membranes. We incorporated varying amounts of RHA into a chitosan solution and prepared thin film membranes via solution casting. We performed structural, chemical, and mechanical characterizations on the ash and membranes, observing 82.84 % water uptake in the 1.5 weight percent (wt%) RHA-doped membrane and 13.93 MPa tensile strength in the 2.0 wt% loaded composite. As the RHA content increased, the swelling ratio of the composites with RHA loadings greater than 1.0 wt% decreased, indicating an enhancement in mechanical strength. The observed results demonstrate that combining improved mechanical strength with increased water absorption and reduced swelling can lead to optimal membrane characteristics.