Single-Site Catalysts on a Cylindrical Support Beyond Nanosize
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Publication date
2003
Authors
Koten, G. van
Suijkerbuijk, B.M.J.M.
Shu, L.
Klein Gebbink, R.J.M.
Dieter, A.
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Abstract
Dendronized polymers (DenPol's) up to generation 3 were equipped with NCN-palladium and -platinum pincer complexes at their peripheries, using active ester chemistry. The palladium compounds catalyze the aldol condensation of benzaldehyde with methyl isocyanoacetate and show a generation-independent activity.