New Peptide Labels Containing Covalently Bonded Platinum(II) Centers as Diagnostic Biomarkers and Biosensors
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Publication date
2000
Authors
Koten, G. van
Albrecht, M.A.
Rodriguez, G.
Schoenmaker, J.
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Article
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Abstract
The binuclear Ru(II) N2-bridged complex [{RuCl2(NN'N)}2(-N2)] (1; NN'N = 2,6-bis[(dimethylamino)methyl]pyridine) promotes the atom transfer radical polymerization (ATRP) of methyl methacrylate under mild conditions. The intermediate paramagnetic Ru(III) species mer-[RuCl3(NN'N)] (2) has been isolated and characterized by X-ray diffraction methods. The reaction of 1 with CH2Cl2 gives the dichloromethyl Ru(II) complex [RuCl(CHCl2)(NN'N)] (3).