A sedimentary tetrahydrophenanthrene derivative of tetrahymano

Publication date

1999

Authors

Sinninghe Damsté, J.S.
Koster, J.
Baas, M.
Ossebaar, J.
Dekker, M.
Pool, W.
Geenevasen, J.A.J.

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Abstract

A novel tetrahydrophenanthrene derivative 1 (1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene), formed from the triterpenoid tetrahymanol 2a by dehydration, ring A and B degradation and aromatisation during sediment diagenesis, has been isolated from a 180 Ma old marine sedimentary rock and identified by 1H and 13C NMR spectroscopy and mass spectrometry.

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