1,1'-Bis(ferrocenylphenylphosphino)-ferrocene
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Publication date
2007
Authors
von Chrzanowski, L.S.
Lutz, Martin
Spek, Anthony Louis
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Article
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Abstract
In the title compound, [Fe3(C5H5)2(C16H13P)2], two (C6H5)P-[(C5H4)Fe(C5H5)](C5H4) units are bridged by an Fe atom, located on an inversion center, giving a central third ferrocene unit. Each Fe atom is coordinated by two cyclopentadienyl rings in a parallel sandwich fashion, with twisted conformations. The geometry of the phosphine P atom is pseudotetrahedral, defined by a phenyl ring, two cyclopentadienyl rings and an electron pair.
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von Chrzanowski, L S, Lutz, M & Spek, A L 2007, '1,1'-Bis(ferrocenylphenylphosphino)-ferrocene', Acta crystallographica. Section E, Structure reports, vol. E63, pp. m2098.