Self-assembly of isotropic colloids into colloidal strings, Bernal spiral-like, and tubular clusters
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2020-06-11
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Abstract
We report the (spontaneous) formation of colloidal strings, Bernal spiral-like, and tubular clusters comprising spherical, isotropically functionalized colloidal particles in an aqueous environment. The formation of colloidal strings and Bernal spiral-like clusters is guided by an interplay between short-ranged hydrophobic attraction and relatively longer-ranged electrostatic repulsion acting between the colloids. When a dispersion of these colloids is densifiedviacentrifugation, well-defined tubular aggregates were observed.
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Taverne, Catalysis, Electronic, Optical and Magnetic Materials, Ceramics and Composites, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Materials Chemistry
Citation
Guo, Y, van Ravensteijn, B G P & Kegel, W K 2020, 'Self-assembly of isotropic colloids into colloidal strings, Bernal spiral-like, and tubular clusters', Chemical Communications, vol. 56, no. 46, pp. 6309-6312. https://doi.org/10.1039/d0cc00948b