Self-assembly of isotropic colloids into colloidal strings, Bernal spiral-like, and tubular clusters

Publication date

2020-06-11

Authors

Guo, Y.ISNI 0000000419566784
van Ravensteijn, BasISNI 000000038783785X
Kegel, WillemISNI 0000000388841893

Editors

Advisors

Supervisors

Document Type

Article
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License

taverne

Abstract

We report the (spontaneous) formation of colloidal strings, Bernal spiral-like, and tubular clusters comprising spherical, isotropically functionalized colloidal particles in an aqueous environment. The formation of colloidal strings and Bernal spiral-like clusters is guided by an interplay between short-ranged hydrophobic attraction and relatively longer-ranged electrostatic repulsion acting between the colloids. When a dispersion of these colloids is densifiedviacentrifugation, well-defined tubular aggregates were observed.

Keywords

Taverne, Catalysis, Electronic, Optical and Magnetic Materials, Ceramics and Composites, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Materials Chemistry

Citation

Guo, Y, van Ravensteijn, B G P & Kegel, W K 2020, 'Self-assembly of isotropic colloids into colloidal strings, Bernal spiral-like, and tubular clusters', Chemical Communications, vol. 56, no. 46, pp. 6309-6312. https://doi.org/10.1039/d0cc00948b