Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks
Publication date
2007
Authors
Angamuthu, R.
Kooijman, Huub
Lutz, M.
Spek, A.L.
Bouwman, E.
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Article
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Abstract
The hexanuclear [Ni6L12] (2) wheel-type cluster adopts an unusual structural motif whereby four NiS4 square-planar and two NiS5 square-pyramidal units are conjoined by edge sharing; the NiS5 units resemble the Ni centre of the inactive state in the [NiFe] hydrogenase.
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Angamuthu, R, Kooijman, H, Lutz, M, Spek, A L & Bouwman, E 2007, 'Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks', Journal of the Chemical Society. Dalton transactions : inorganic chemistry, pp. 4641-4643.