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Consecutive dynamic resolutions of phosphine oxides

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Publication date

2014-04-01

Authors

Kortmann, Felix A.
Chang, Mu Chieh
Otten, Edwin
Couzijn, Erik P A
Lutz, M.ORCID 0000-0003-1524-9629ISNI 0000000352600916
Minnaard, Adriaan J.

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DOI

https://doi.org/10.1039/c3sc52913d

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Article

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Utrecht University Repository

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Abstract

A crystallization-induced asymmetric transformation (CIAT) involving a radical-mediated racemization provides access to enantiopure secondary phosphine oxides. A consecutive CIAT is used to prepare enantio- and diastereo-pure tert-butyl(hydroxyalkyl)phenylphosphine oxides.

Keywords

General Chemistry

Citation

Kortmann, F A, Chang, M C, Otten, E, Couzijn, E P A, Lutz, M & Minnaard, A J 2014, 'Consecutive dynamic resolutions of phosphine oxides', Chemical Science, vol. 5, no. 4, pp. 1322-1327. https://doi.org/10.1039/c3sc52913d

URI

https://dspace.library.uu.nl/handle/1874/308066