Direct evidence on the existence of [Mo132] Keplerate-type species in aqueous solution
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Publication date
2007
Authors
Roy, S.
Planken, K.L.
Kim, R.
van der Mandele, D.
Kegel, Willem
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Abstract
We demonstrate the existence of discrete single molecular [Mo132] Keplerate-type clusters in aqueous solution. Starting from a discrete spherical [Mo132] cluster, the formation of an open-basket-type [Mo116] defect structure is shown for the first time in solution using analytical ultracentrifugation sedimentation velocity experiments.
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Roy, S, Planken, K L, Kim, R, van der Mandele, D & Kegel, W K 2007, 'Direct evidence on the existence of [Mo132] Keplerate-type species in aqueous solution', Inorganic Chemistry, vol. 46, pp. 8469-8471.