Derivatization reactions in the gas—liquid chromatographic analysis of drugs in biological fluids

Publication date

1984

Authors

Hulshoff, A.
Lingeman, H.

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DOI

Document Type

Article
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Abstract

Alkylation, acylation, silylation and other derivatization reactions applied to the gas chromatographic analysis of drugs in biological matrices are reviewed. Reaction conditions are discussed in relation to reaction mechanisms. Detector-oriented labelling of drugs, and derivatization with chiral reagents for the separation of enantiomers are surveyed. Data on the sample clean-up, derivatization and GLC analysis of more than 300 drugs and related compounds are listed.

Keywords

Derivatization for gas—liquid chromatography; drug analysis; biological fluids; specific detectors in gas—liquid chromatography;, gas—liquid chromatography—mass spectrometry; sample clean-up procedures

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