Unexpected reactivity of a PONNOP ‘expanded pincer’ ligand
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Publication date
2020-05-01
Authors
Scheerder, Arthur R.
Lutz, Martin
Broere, Danny
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Abstract
We report the synthesis, characterization and coordination chemistry of a new naphthyridine-derived phosphinite PONNOP expanded pincer ligand. As envisioned, the dinucleating ligand readily binds two copper(I) centers in close proximity, but undergoes an unexpected rearrangement in the presence of nickel(II) salts to form an interesting PONNP pincer platform.
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Scheerder, A R, Lutz, M & Broere, D L J 2020, 'Unexpected reactivity of a PONNOP ‘expanded pincer’ ligand', Chemical Communications, vol. 56, no. 59, pp. 8198-8201. https://doi.org/10.1039/D0CC02166K